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66-84-2

Basic Information
CAS No.: 66-84-2
Name: D-Glucosamine hydrochloride
Molecular Structure:
Molecular Structure of 66-84-2 (D-Glucosamine hydrochloride)
Formula: C6H13NO5.HCl
Molecular Weight: 215.63 .
Synonyms: D-Glucose, 2-amino-2-deoxy-, hydrochloride;Chitosamine hydrochloride;2-Amino-2-deoxy-beta-D-glucopyranose hydrochloride;2-Amino-D-glucose;2-Deoxy-2-amino-D-glucose hydrochloride;D-Glucosamine monohydrochloride;D-Glucose, 2-amino-2-deoxy-, hydrochloride (1:1);2-Amino-2-deoxy-D-glucose hydrochloride;
EINECS: 200-638-1
Density:
Melting Point: 190-194 °C (dec.)(lit.)
Boiling Point: 449.9 °C at 760 mmHg
Flash Point: 225.9 °C
Solubility: Soluble in water
Appearance: white powder
Hazard Symbols: IrritantXi, HarmfulXn, FlammableF
Risk Codes: 21-36/38-46-62-63
Safety: 24/25-53-36/37-26-25
Transport Information:
PSA: 124.01000
LogP: -1.91010
Synthetic route
Conditions
ConditionsYield
With hydrogenchloride; methanol als Hydrochlorid;
α-modification of d-glucosamine

α-modification of d-glucosamine

66-84-2

D-(+)-glucosamine hydrochloride

Conditions
ConditionsYield
With water anschliessend Behandeln mit Alkohol;
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Chemistry


IUPAC Name: (2R,3R,4R,5S,6R)-3-Amino-6-(hydroxymethyl)oxane-2,4,5-triol hydrochloride
Molecular Formula: C6H14ClNO5
Molecular Weight: 215.63 g/mol
Canonical SMILES: C(C1C(C(C(C(O1)O)N)O)O)O.Cl
InChI: InChI=1/C6H13NO5.ClH/c7-3(1-8)5(11)6(12)4(10)2-9;/h1,3-6,9-12H,2,7H2;1H/t3-,4+,5+,6+;/m0./s1
Mol File: 66-84-2.mol
EINECS: 200-638-1
Classification Code: Drug / Therapeutic Agent; Mutation data
Product Categories: Anilines, Aromatic Amines and Nitro Compounds; Aminosugars; Biochemistry; Glucose; Sugars; Nutritional Supplements; Dextrins、Sugar & Carbohydrates; Food & Flavor Additives
Stability: Stable. Incompatible with strong oxidizing agents. Combustible.
Refractive index: 72 ° (C=1, H2O)
Storage temperature: Store at RT.
Solubility: H2O: 0.1 g/mL, clear, colorless
Form: crystalline
Water Solubility: soluble
H-Bond Donor: 6
H-Bond Acceptor: 6
Rotatable Bond Count: 1
Exact Mass: 215.05605
MonoIsotopic Mass: 215.05605
Topological Polar Surface Area: 116
Heavy Atom Count: 13
Complexity: 155
Flash Point: 225.9 °C
Enthalpy of Vaporization: 81.76 kJ/mol
Boiling Point: 449.9 °C at 760 mmHg
Melting Point: 190-194 °C (dec.)(lit.)
alpha: 72.5 °(c=2, H2O, 5hrs.)
Vapour Pressure of D-Glucosamine Hydrochloride (CAS NO.66-84-2): 5.53E-10 mmHg at 25 °C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
frog LD50 parenteral 5gm/kg (5000mg/kg) PERIPHERAL NERVE AND SENSATION: SENSORY CHANGE INVOLVING PERIPHERAL NERVE Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 56(1), Pg. 64S, 1960.
mouse LD50 intravenous 1100mg/kg (1100mg/kg)   Chemotherapia. Vol. 5, Pg. 277, 1962.
mouse LD50 oral 15gm/kg (15000mg/kg) PERIPHERAL NERVE AND SENSATION: SENSORY CHANGE INVOLVING PERIPHERAL NERVE Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 56(1), Pg. 64S, 1960.
mouse LD50 subcutaneous 6200mg/kg (6200mg/kg) PERIPHERAL NERVE AND SENSATION: SENSORY CHANGE INVOLVING PERIPHERAL NERVE Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 56(1), Pg. 64S, 1960.

Safety Profile

Hazard Codes: FlammableF,IrritantXi,HarmfulXn
Risk Statements: 21-36/38-46-62-63 
R21: Harmful in contact with skin. 
R36/38: Irritating to eyes and skin. 
R46: May cause heritable genetic damage. 
R62: Risk of impaired fertility. 
R63: Possible risk of harm to the unborn child.
Safety Statements: 24/25-53-36/37-26-25 
S24/25: Avoid contact with skin and eyes. 
S53: Avoid exposure - obtain special instructions before use. 
S36/37: Wear suitable protective clothing and gloves. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S25: Avoid contact with eyes.
WGK Germany: 2
Hazard Note of D-Glucosamine Hydrochloride (CAS NO.66-84-2): Highly Flammable

Specification

 D-Glucosamine Hydrochloride (CAS NO.66-84-2), its Synonyms are Glucosamine hydrochloride ; D-Glucose, 2-amino-2-deoxy-, hydrochloride ; D-Glucose, 2-amino-2-deoxy-, hydrochloride (1:1) ; 2-Amino-2-deoxy-D-glucose hydrochloride ; 2-Amino-2-deoxy-beta-D-glucopyranose hydrochloride ; 2-Amino-D-glucose ; 2-Deoxy-2-amino-D-glucose hydrochloride . It is white powder.