
Journal of the American Chemical Society p. 11780 - 11783 (2013)
Update date:2022-07-31
Topics: Synthesis Elemental analysis Enantiomer Characterization Yield Distillation Mass spectrometry Reactivity Ligand Nucleophile Electrophile Thermolysis Steric hindrance Carbene Chromatography Recrystallization Electron density Adsorption Radical Photolysis Filtration GC (gas chromatography) Precursor Fluorescence Hydrogen bonding eluent TLC (thin-layer chromatography) HPLC (high-performance liquid chromatography) NMR (nuclear magnetic resonance) Fractional distillation Vacuum distillation Square planar Intermediate Resonance Resolution X-ray crystallography Leaving group Tautomerism Dielectric constant Chelation Isomer Metathesis Steric Effects Oxidative Addition Reductive Elimination Reaction Mechanism Electronic effects Crystal packing Catalysis Spectroscopy
Hayes, Paul G.
Xu, Zhenggang
Beddie, Chad
Keith, Jason M.
Hall, Michael B.
Tilley, T. Don
The first silylyne complex of a metal beyond group 6, [Cp*( iPr3P)(H)Os≡Si(Trip)][HB(C6F 5)3], was prepared by a new synthetic route involving hydride abstraction from silicon. NMR and DFT computation
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Doi:10.1039/c4ob01744g
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(2013)