Allylic Rearrangements During the Rhodium-catalysed Reactions of 2-Allyloxybenzylamines and 2-(N-Allyl-N-benzylamino)benzylamine

DOI: 10.1039/C39940002763

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2763 - 2764 (1994)

Update date:2022-07-30

Topics:

Authors:

Campi, Eva M.

Jackson, W. Roy

McCubbin, Quentin J.

Trnacek, Andrew E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/C39940002763

Reactions of 2-allyloxybenzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines via a reaction which involves allylic cleavage and carbonylation as demonstrated by crossover experiments.

Full text of DOI:10.1039/C39940002763

View Article Online / Journal Homepage / Table of Contents for this issue

Products guided by the article

Product name:2-(1'-methylethyl)-3,4-dihydro-2H-1,3-benzoxazine

Cas No:14680-15-0

R&D Labs maybe for 14680-15-0

Chengdu Cogon Bio-tech Co., Ltd.

Contact:86-28-85171192

Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
Mashilabs(shanghai)Co.,ltd

Contact:+86-21-54391580

Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China

Relevant to this article

Substituted 2-hydroxy-N-(arylalkyl)benzamides induce apoptosis in cancer cell lines

Doi:10.1016/j.ejmech.2013.08.009
(2013)
Doi:10.1039/CT8803700592
(1880)
The carbonate analogues of 5′-halogenated resiniferatoxin as TRPV1 ligands

Doi:10.1016/j.ejmech.2013.07.042
(2013)
Dehydrogenation and oxidative coupling of alcohol and amines catalyzed by organosilicon-supported TiO₂@PMHSIPN

Doi:10.1039/c4ra06685e
(2014)
Nucleosides and Nucleotides. 116. Convenient Syntheses of 3-Deazaadenosine, 3-Deazaguanosine, and 3-Deazainosine via Ring Closure of 5-Ethynyl-1-β-D-ribofuranosylimidazole-4-carboxamide or -carbonitrile

Doi:10.1016/S0040-4020(01)86259-1
(1993)
Tandem Inter <4+2>/Intra <3+2> Nitroalkene Cycloadditions. 5. Origin of the Lewis Acid Dependent Reversal of Stereoselektivity

Doi:10.1021/jo00059a044
(1993)

Article Doi