Allylic Rearrangements During the Rhodium-catalysed Reactions of 2-Allyloxybenzylamines and 2-(N-Allyl-N-benzylamino)benzylamine

DOI: 10.1039/C39940002763

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2763 - 2764 (1994)

Update date:2022-07-30

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Authors:

Campi, Eva M.

Jackson, W. Roy

McCubbin, Quentin J.

Trnacek, Andrew E.

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Article abstract of DOI:10.1039/C39940002763

Reactions of 2-allyloxybenzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines via a reaction which involves allylic cleavage and carbonylation as demonstrated by crossover experiments.

Full text of DOI:10.1039/C39940002763

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