Journal of Physical Chemistry p. 2971 - 2976 (1989)
Update date:2022-09-26
Topics:
Mielke, Zofia
Andrews, Lester
P4O6 was reacted with oxygen atoms (16O and 18O) obtained from ozone photolysis and discharge of oxygen.The P4O7-10 and P4O6(18)O1-4 products were trapped in solid argon and examined by infrared spectroscopy.The spectra of the four higher oxides support a central P4O6 cage structure with additional terminal P=16O or P=18O bonds.The P=16O and P=18O vibrations are identified in four higher oxides, and assignments are proposed for several of the more intense P4O6 cage absorptions.
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