Generation of Sulfonyl Radicals from Sodium Sulfinates by Oxidation with Metallic Oxidants and Their Addition Reaction with Olefins

DOI: 10.1246/cl.1994.1705

Source and publish data:

Chemistry Letters p. 1705 - 1708 (1994)

Update date:2022-08-03

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Authors:

Narasaka, Koichi

Mochizuki, Takashi

Hayakawa, Satoshi

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Article abstract of DOI:10.1246/cl.1994.1705

Sodium arylsulfinates are treated with manganese(III) 2-pyridinecarboxylate or cerium(IV) tetrabutylammonium nitrate to generate sulfonyl radicals, which react with various olefins giving the addition products.

Full text of DOI:10.1246/cl.1994.1705

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