Dalton Transactions p. 12156 - 12159 (2014)
Update date:2022-07-30
Topics:
Farran, Rajaa
Jouvenot, Damien
Loiseau, Frederique
Chauvin, Jerome
Deronzier, Alain
A tri-metallic triad based on a [Ru(bpy)3]2+ moiety connected to Fe(ii) and Co(iii) bisterpyridine has been grafted on an ITO electrode by a stepwise procedure. Under visible light, in the presence of a sacrificial electron donor, the system produces electric current. The photo-current magnitude is compared to the one generated from a Co(iii)-Ru(ii) dyad and shows an increase of 40%.
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