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80-09-1

Basic Information
CAS No.: 80-09-1
Name: 4,4'-Sulfonyldiphenol
Molecular Structure:
Molecular Structure of 80-09-1 (4,4'-Sulfonyldiphenol)
Formula: C12H10O4S
Molecular Weight: 250.27
Synonyms: 4-(4-hydroxyphenyl)sulfonylphenol;4,4'-Sulfonyldiphenol;
EINECS: 201-250-5
Density: 1.432 g/cm3
Melting Point: 245-250 °C(lit.)
Boiling Point: 505.3 °C at 760 mmHg
Flash Point: 259.4 °C
Solubility: 1.1 g/L (20°C) in water
Appearance: light yellow crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-39-36
Transport Information:
PSA: 82.98000
LogP: 3.01140
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  • 4,4'-Sulfonyldiphenol

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Consensus Reports

Reported in EPA TSCA Inventory.

Specification

1. Introduction of 4,4'-Sulfonyldiphenol
4,4'-Sulfonyldiphenol is commonly used as a reactant in epoxy reactions, and is used in curing fast-drying epoxy resin glues. The IUPAC Name of 4,4'-Sulfonyldiphenol is 4-(4-Hydroxyphenyl)sulfonylphenol.

2. Properties of 4,4'-Sulfonyldiphenol
H bond acceptors: 4
H bond donors: 2
Freely Rotating Bonds: 4
Polar Surface Area: 60.98 Å2
Index of Refraction: 1.645
Molar Refractivity: 63.33 cm3
Molar Volume: 174.6 cm3
Surface Tension: 60.7 dyne/cm
Density: 1.432 g/cm3
Flash Point: 259.4 °C
Enthalpy of Vaporization: 80.43 kJ/mol
Boiling Point: 505.3 °C at 760 mmHg
Vapour Pressure: 7.8E-11 mmHg at 25°C
Melting Point: 245-250 °C(lit.)
Water Solubility: 1.1 g/L (20°C)
Appearance: light yellow crystalline powder
Stability: Stable. Incompatible with strong bases, acid chloride, acid anhydrides, strong oxidizing agents. 
Product Categories of 4,4'-Sulfonyldiphenol (CAS NO.80-09-1): Aromatics;Sulphur Derivatives;API intermediates;Color Former & Related Compounds;Developer;Diphenyl Sulfones (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research

3. Structure Descriptors of 4,4'-Sulfonyldiphenol
4. Toxicity of 4,4'-Sulfonyldiphenol

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 skin > 1mg/kg (1mg/kg)   National Technical Information Service. Vol. OTS0534330,
mouse LD50 intraperitoneal 200mg/kg (200mg/kg)   National Technical Information Service. Vol. OTS0534330,
mouse LD50 oral 1600mg/kg (1600mg/kg)   National Technical Information Service. Vol. OTS0534330,
rabbit LD50 skin > 10250mg/kg (10250mg/kg)   BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. Vol. 601-05501, Pg. 1974,
rabbit LDLo oral 4700mg/kg (4700mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

KIDNEY, URETER, AND BLADDER: OTHER CHANGES IN URINE COMPOSITION
National Technical Information Service. Vol. OTS0555048,
rat LD50 intraperitoneal 400mg/kg (400mg/kg)   National Technical Information Service. Vol. OTS0534330,
rat LD50 oral 4556mg/kg (4556mg/kg)   BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. Vol. 601-05501, Pg. 1974,

5. Safety Information of 4,4'-Sulfonyldiphenol

Hazard Codes: IrritantXi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-39-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36: Wear suitable protective clothing. 
S39: Wear eye / face protection.
WGK Germany: 2
RTECS: SM8925000
HS Code: 29309070
Mildly toxic by ingestion. A skin and eye irritant. When heated to decomposition it emits toxic fumes of SOx

6. Preparation of 4,4'-Sulfonyldiphenol
4,4'-Sulfonyldiphenol can produced by the reaction of two equivalents of phenol with one equivalent of sulfuric acid.


7. Use of  4,4'-Sulfonyldiphenol
 4,4'-Sulfonyldiphenol is mainly used as monomer for synthesizing polysulfone resin. It can be also directly applied in coatings, leather modifier, dye intermediates, metal electroplating light agent, etc.

8. Other details of 4,4'-Sulfonyldiphenol
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dangerous fire hazard in the form of dust when exposed to heat or flame.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage: Store in a cool, dry place. Store in a tightly closed container.