A facile synthesis of 5-thio-L-fucose and 5-thio-D-arabinose from D-arabinose

DOI: 10.1016/0008-6215(95)00323-1

Source and publish data:

Carbohydrate Research p. 287 - 302 (1996)

Update date:2022-08-04

Topics:

Authors:

Izumi, Masayuki

Tsuruta, Osamu

Hashimoto, Hironobu

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Article abstract of DOI:10.1016/0008-6215(95)00323-1

5-Thio-L-fucopyranose tetraacetate was synthesized in 11 steps from 5-O-trityl-D-arabinofuranose or D-arabinose diethyl dithioacetal by one-carbon elongation at C-5. Highly diastereoselective addition of MeLi in ether to a 1,2-O-isopropylidene-β-D-arabino

Full text of DOI:10.1016/0008-6215(95)00323-1

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