Effects of a sterically demanding P-aryl substituent in phosphole and 7-phosphanorbornene chemistry

Article abstract of DOI:10.1080/10426509608545183

The 2,4-di-tert-butyl-6-methylphenyl substituent was placed on phosphorus of a phosphole, causing restricted rotation about the P-C bond and flattening of the phosphorus pyramid. Electron delocalization was greater in this phosphole as a result of the fla

Full text of DOI:10.1080/10426509608545183

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Phosphorus, Sulfur, and Silicon and
the Related Elements
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Effects of a Sterically Demanding
P–Aryl Substituent in Phosphole
and 7–Phosphanorbornene
Chemistry
Louis D. Quin , Alexey S. Ionkin , Rajdeep Kalgutkar &
György Keglevich
a Department of Chemistry, Box 34510 , University of
Massachusetts , Amherst, MA 01003-4510, USA
b Department of Chemistry, Box 34510 , University of
Massachusetts , Amherst, MA 01003-4510, USA
c Department of Chemistry, Box 34510 , University of
Massachusetts , Amherst, MA 01003-4510, USA
d Department of Organic Chemical Technology , Technical
University of Budapest , 1520 Budapest, Hungary
Published online: 06 Aug 2008.
To cite this article: Louis D. Quin , Alexey S. Ionkin , Rajdeep Kalgutkar & György
Keglevich (1996) Effects of a Sterically Demanding P–Aryl Substituent in Phosphole and
7–Phosphanorbornene Chemistry, Phosphorus, Sulfur, and Silicon and the Related Elements,
109:1-4, 433-436, DOI: 10.1080/10426509608545183
To link to this article: http://dx.doi.org/10.1080/10426509608545183
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