Tetrahedron Asymmetry p. 2775 - 2778 (1996)
Update date:2022-08-03
Topics:
Amat, Mercedes
Coll, Ma-Dolors
Passarella, Daniele
Bosch, Joan
An enantioselective synthesis of the Strychnos alkaloid (-)-tubifoline, involving the kinetic resolution of racemic 1-(3-pyridyl)ethanol, the orthoester Claisen rearrangement of the enantiopure allylic alcohol 5, Smith indolization of the resulting 4-piperidineacetate 6, photocyclization of chloroacetamide 9, and final transannular cyclization, is reported.
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Doi:10.1016/0277-5387(96)00292-6
(1997)Doi:10.1021/ja962681x
(1996)Doi:10.1039/c9ra10663d
(2020)Doi:10.1021/ja9624331
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(1967)Doi:10.1016/S0040-4039(00)73089-9
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