Synthesis and Characterization of New Phosphanylium and Phosphanetriylammonium Salts. Molecular Structures of and (1+)(1-) (R = C6H2-t-Bu3-2,4,6)

DOI: 10.1039/DT9940002925

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2925 - 2932 (1994)

Update date:2022-07-30

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Authors:

Drapailo, Andrei B.

Chernega, Alexander N.

Romanenko, Vadim D.

Madhouni, Rachid

Sotiropoulos, Jean-Marc

et al. et al.

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Article abstract of DOI:10.1039/DT9940002925

The new internal salts <(R1R2N)PN(ECl3)R> (E = Al or Ga; R = 2,4,6-t-Bu3C6H2) and phosphanylium salts (1+)(1-) have been synthesized by treating aminoiminophosphanes (R1R2N)P=NR with AlCl3, GaCl3 or CF3SO3H.Protonation of RHN-P=NR w

Full text of DOI:10.1039/DT9940002925

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