Diphenyl methylphosphonate as a phosphonylation reagent with high diastereoselectivity at phosphorus

DOI: 10.1016/S0040-4039(97)00423-1

Source and publish data:

Tetrahedron Letters p. 2597 - 2600 (1997)

Update date:2022-07-30

Topics:

Authors:

Moriarty, Robert M.

Tao, Anping

Condeiu, Cristian

Gilardi, Richard

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Article abstract of DOI:10.1016/S0040-4039(97)00423-1

Reaction of diphenyl methylphosphonate with lithium alkoxides generated in situ from alcohols and butyllithium gives phenyl alkyl methylphosphonate diesters even with hindered alcohols and with high diastereoselectivity at phosphorus.

Full text of DOI:10.1016/S0040-4039(97)00423-1

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Product name:(S)-Methyl-phosphonic acid (S)-2-cyano-1-((S)-1-dibenzylamino-ethyl)-2,2-dimethyl-ethyl ester phenyl ester

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