Journal of Organometallic Chemistry p. 157 - 161 (1998)
Update date:2022-08-04
Topics:
Wan, Wen
Guang, Wen-Jie
Zhao, Ke-Qin
Zheng, Wei-Zhong
Zhang, Liang-Fu
A series of novel organometallic complexes based on γ-substituted β-diketone ligands with terminal metal Rh(I) have been prepared by reaction of the ligands with [Rh(CO)2(μ-Cl)]2. The mesomorphism of the ligands and complexes has been investigated using DSC and polarizing microscope. It is found that non-mesogenic ligands with n=7, 8, 9, 10, 11 can form liquid crystalline phase by direct coordination to metal. The effect of the terminal carbon number on the mesomorphism has also been discussed.
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