New benzodioxepin type strobilurins from basidiomycetes. Structural revision and determination of the absolute configuration of strobilurin D and related β-methoxyacrylate antibiotics

DOI: 10.1016/S0040-4020(99)00563-3

Source and publish data:

Tetrahedron p. 10101 - 10118 (1999)

Update date:2022-07-29

Topics:

Authors:

Hellwig, Veronika

Dasenbrock, Johannes

Klostermeyer, Doerte

Kroiss, Stefan

Sindlinger, Tilman

Spiteller, Peter

Steffan, Bert

Steglich, Wolfgang

Engler-Lohr, Michaela

Semar, Sylvia

Anke, Timm

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Article abstract of DOI:10.1016/S0040-4020(99)00563-3

The new antifungal strobilurins I (1) and K (19) are 3,4-dihydro-2H- benzo[b][1,4]dioxepin derivatives. Their structure and stereochemistry was determined by degradation to aldehyde 3. Both enantiomers of 3 were synthesised and the absolute configurations

Full text of DOI:10.1016/S0040-4020(99)00563-3

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