
Tetrahedron p. 10101 - 10118 (1999)
Update date:2022-07-29
Topics:
Hellwig, Veronika
Dasenbrock, Johannes
Klostermeyer, Doerte
Kroiss, Stefan
Sindlinger, Tilman
Spiteller, Peter
Steffan, Bert
Steglich, Wolfgang
Engler-Lohr, Michaela
Semar, Sylvia
Anke, Timm
The new antifungal strobilurins I (1) and K (19) are 3,4-dihydro-2H- benzo[b][1,4]dioxepin derivatives. Their structure and stereochemistry was determined by degradation to aldehyde 3. Both enantiomers of 3 were synthesised and the absolute configurations
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(2013)