Generation of nitrile oxides from oxime derivatives by the oxidation with ammonium hexanitratocerate(IV)

DOI: 10.1246/bcsj.72.2277

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2277 - 2285 (1999)

Update date:2022-08-04

Topics:

Authors:

Arai, Noriyoshi

Iwakoshi, Mitsuhiko

Tanabe, Katsuhiko

Narasaka, Koichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.72.2277

Aromatic and aliphatic nitrile oxides are generated by the oxidation of α-hydroxyimino carboxylic acid with ammonium hexanitratocerate(IV). They react with olefinic and acetylenic dipolarophiles to give the corresponding cycloaddition products in good yield. The oxidation of α-oxo aldoximes also affords α-oxo carbonitrile oxides.

Full text of DOI:10.1246/bcsj.72.2277

Products guided by the article

Product name:5-phenethyl-3-(3-phenylpropyl)-4,5-dihydroisoxazole

Cas No:253270-24-5

R&D Labs maybe for 253270-24-5

HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Taizhou Shengxing Chempharm Co.,Ltd

Contact:+86-576-88516600

Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China

Relevant to this article

Two routes to bis(μ-diphenylphosphino)methane diplatinum halides bridged by sulfur monoxide

Doi:10.1021/om9905815
(1999)
Syntheses and spectra of triphenyltin heteroarenethiolates: Crystal structures of triphenyltin 1-methyltetrazole-5-thiolate and triphenyltin benzoxazole-2-thiolate

Doi:10.1016/S0277-5387(99)00211-9
(1999)
Stereoselective synthesis of 3-(phenylsulphonyl)-2,5 disubstituted tetrahydrofurans via 5-endo-trig ring-closure reactions

Doi:10.1016/S0040-4039(00)92345-1
(1992)
Enantiomerically pure chiral pyridino-crown ethers: Synthesis and enantioselectivity toward the enantiomers of α-(1-naphthyl)ethylammonium perchlorate

Doi:10.1016/S0957-4166(99)00381-X
(1999)
Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

Doi:10.1021/acs.orglett.7b00923
(2017)
Doi:10.1021/jo01129a014
(1953)

Article Doi