
Bulletin of the Chemical Society of Japan p. 2277 - 2285 (1999)
Update date:2022-08-04
Topics:
Arai, Noriyoshi
Iwakoshi, Mitsuhiko
Tanabe, Katsuhiko
Narasaka, Koichi
Aromatic and aliphatic nitrile oxides are generated by the oxidation of α-hydroxyimino carboxylic acid with ammonium hexanitratocerate(IV). They react with olefinic and acetylenic dipolarophiles to give the corresponding cycloaddition products in good yield. The oxidation of α-oxo aldoximes also affords α-oxo carbonitrile oxides.
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(1999)Doi:10.1021/acs.orglett.7b00923
(2017)Doi:10.1021/jo01129a014
(1953)