Generation of nitrile oxides from oxime derivatives by the oxidation with ammonium hexanitratocerate(IV)

DOI: 10.1246/bcsj.72.2277

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2277 - 2285 (1999)

Update date:2022-08-04

Topics:

Authors:

Arai, Noriyoshi

Iwakoshi, Mitsuhiko

Tanabe, Katsuhiko

Narasaka, Koichi

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Article abstract of DOI:10.1246/bcsj.72.2277

Aromatic and aliphatic nitrile oxides are generated by the oxidation of α-hydroxyimino carboxylic acid with ammonium hexanitratocerate(IV). They react with olefinic and acetylenic dipolarophiles to give the corresponding cycloaddition products in good yield. The oxidation of α-oxo aldoximes also affords α-oxo carbonitrile oxides.

Full text of DOI:10.1246/bcsj.72.2277

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