Stereocontrolled synthesis of retinoids functionalized at C-13 by Suzuki coupling reactions

DOI: 10.1016/S0040-4020(99)00861-3

Source and publish data:

Tetrahedron p. 13779 - 13790 (1999)

Update date:2022-08-05

Topics:

Authors:

Alvarez, Rosana

Iglesias, Beatriz

De Lera, Angel R.

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Article abstract of DOI:10.1016/S0040-4020(99)00861-3

The retinal analogues (13Z)-13-bromo- 13-desmethylretinal (3) and (13E)- 20,20,20-trifluororetinal (4) have been efficiently synthesized using the palladium-catalyzed cross-coupling of boronic acid 8 and electrophiles 9 and 10, respectively. For the first

Full text of DOI:10.1016/S0040-4020(99)00861-3

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