Phytochemistry p. 958 - 959 (1989)
Update date:2022-08-05
Topics: Enantiomer Spectroscopic Analysis Chromatographic Separation Experimental Methods Absolute Configuration Biosynthesis Chiral molecule
Saito, Kazuki
Takamatsu, Satoshi
Sekine, Toshikazu
Ikegami, Fumio
Ohmiya, Shigeru
et al.
(+)-5,6-Dehydrolupanine, a key intermediate in biosynthesis of lupin alkaloids, was isolated from Thermopsis chinensis.The absolute configuration of the compound was determined to be 7R,9R,11R by chemical transformation to (-)-lupanine.Key Word Index - Thermopsis chinensis; Leguminosae; aerial parts; lupin alkaloid; quinolizidine alkaloid; (+)-5,6-dehydrolupanine; lupanine; absolute configuration; biosynthesis.
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