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2015, 44, 6804; d) J. Wang, C. Qi, Z. Ge, T. Chen and R. Li, Chem.
from that of the fresh catalyst (Fig. 2c). This observation clearly
demonstrates that there was no leaching or catalyst
decomposition over the catalytic process or isolation.
Furthermore, our UiO-66-RArSO3H material behaved similarly in
the MBH reaction catalyst reuse, again demonstrating good
recycling capability (Fig. S4).
Commun., 2010, 46, 2124.
7
a) J. Juan-Alcaniz, R. Gielisse, A. B.DOLaI:g1o0.,10E3.9/CV6. RRA1a4m36o5sB-
Fernandez, P. Serra-Crespo, T. Devic, N. Guillou, C. Serre, F.
Kapteijn and J. Gascon, Catal. Sci. Technol,. 2013,
Y. D. Zang, J. Shi, F. M. Zhang, Y. J. Zhong and W. D. Zhu, Catal.
Sci. Technol., 2013, , 2044; c) Y. X. Zhou, Y. Z. Chen, Y. Hu, G.
3, 2311; b)
3
Huang, S. H. Yu and H. L. Jiang, Chem. Eur. J., 2014, 20, 14976;
d) M. Zheng, Y. Liu, C. Wang, S. Liub and W. Lin, Chem. Sci.,
2012, 3, 2623; e) Y. Liu, X. Xi, C. Ye, T. Gong, Z. Yang and Y. Cui,
Conclusions
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Zhang, J. J. Dynes, J. Wang, Y. Hu, D. Ma, Z. Shi, L. Zhu, D. Zhang,
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137, 4243; g) J. Wang, Q. Li, C. Qi,; Z. Ge and R. Li, Org. Biomol.
In conclusion, a novel heterogeneous UiO-66-RArSO3H catalyst
bearing an aromatic sulfonic acid group was synthesized in this
research. The structural morphology of UiO-66-RArSO3H was well
retained after post-synthetic modification using commercial
available o-sulfobenzoic acid anhydride reagent. The newly
developed UiO-66-RArSO3H showed high activity and selectivity in
the acetalization and MBH reactions at only 0.1 mol% catalyst
loadings, which provides higher TONs and TOFs than several other
heterogeneous Brønsted acid catalysts. The UiO-66-RArSO3H catalyst
Chem., 2010, 8, 4240.
8
9
J. Jiang and O. M. Yaghi, Chem. Rev., 2015, 115, 6966.
a) M. B. Gawande, A. K. Rathi, I. D. Nogueira, R. S. Varma and
P. S. Branco, Green Chem. 2013, 15, 1895; b) M. G. Goesten, J.
Juan-Alcaniz, E. V. Ramos-Fernandez, K. B. S. S. Gupta, E.
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10 S. M. Cohen, Chem. Rev., 2012, 112, 970.
was chemically stable, due to its strong covalent bond, and did not 11 K. K. Tanabe and S. M. Cohen, Chem. Soc. Rev., 2011, 40, 498;
V. Valtchev, G. Majano, S. Mintova and P. Ramirez, J. Chem.
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suffer from a leaching problem during liquid catalysis. Further studies
involving new applications of the UiO-66-RArSO3H catalyst are in
progress.
12 D. Britt, C. Lee, F. J. Uribe-Romo, H. Furukawa and O. M. Yaghi,
Inorg. Chem., 2010, 49 6387.
13 a) Y. Luan, N. Zheng, Y. Qi, J. Yu and G. Wang, Eur. J. Inorg.
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Acknowledgements
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We thank the National Natural Science Foundation of China (No.
51503016), Fundamental Research Funds for the Central
Universities FRF-TP-15-001A2 and Key Laboratory of
Photochemical Conversion and Optoelectronic Materials, TIPC,
CAS for financial support.
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