Journal of Organic Chemistry p. 5727 - 5732 (2002)
Update date:2022-08-02
Topics:
Jones, Graham B.
Wright, Justin M.
Hynd, George
Wyatt, Justin K.
Warner, Philip M.
Huber, Robert S.
Li, Aiwen
Kilgore, Michael W.
Sticca, Robert P.
Pollenz, Richard S.
Efficient routes to three classes of 10-membered oxa-enediynes are presented. The electronic and stereoelectronic contributions to half-lives are supported by density functional theory calculations. One member of this class cyclizes to give an isochroman which binds to and degrades the aryl hydrocarbon receptor (AhR).
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Doi:10.1002/jlcr.435
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