Carbanion mechanisms XVIII. Generation of silyl anions by nucleophilic cleavage of disilanes

DOI: 10.1016/0022-328X(92)83433-I

Source and publish data:

Journal of Organometallic Chemistry p. 85 - 89 (1992)

Update date:2022-08-04

Topics:

Authors:

Buncel, Erwin

Venkatachalam, T. Krishnan

Edlund, U.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(92)83433-I

Organosilyl potassium compounds are conveniently generated by cleavage of hexaorganodisilanes with potassium t-butoxide in common solvents other than HMPA (i.e. in THF or DME).Nucleophilic attack on unsymmetrical disilanes results in formation of the more

Full text of DOI:10.1016/0022-328X(92)83433-I

Products guided by the article

Product name:Potassium, (trimethylsilyl)-

Cas No:56859-17-7

R&D Labs maybe for 56859-17-7

Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
Hubei ShiNan Pharmaceutical Chemical co., Ltd.(expird)

Contact:+86-13554447107

Address:Wuhan HongShanOu wu no road 378 future residence building 1 unit 14 layer no. 1401 A
Changsha Easchem Co.,Limited

website:http://www.easchem.com

Contact:+86-731-89722861 89722891

Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.

Contact:+86-576-87501888 / 87501988

Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Anhui Charm Imp.&Exp.Co., Ltd

website:http://www.chinacharm.cn/

Contact:86 551 5316260

Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China

Relevant to this article

Studies on peptides. LII. Application of the trifluoromethanesulphonic acid procedure to the synthesis of a peptide with somatostatin activity

Doi:10.1248/cpb.23.1596
(1975)
Doi:10.1021/ja01641a046
(1954)
Synthesis of functionalized thietanes via electrophilic carbenoid-induced ring expansion of thiiranes with sulfonium acylmethylides as carbene precursors

Doi:10.1021/acs.joc.9b01152
(2019)
Introduction of a chiral centre on C-6 of a carbohydrate unit: Application to the synthesis of the C-2 to C-15 fragment of ionomycin

Doi:10.1016/S0040-4020(01)87081-2
(1991)
Reaction of Solid Acetylanthranil with Methanol Vapor: High Specificity and Enhanced Reactivity

Doi:10.1021/jo00203a021
(1985)
Polyacetylene compounds, XCVII. On the biogenesis of phenylpolyine

Doi:10.1002/cber.19660990339
(1966)

Article Doi