Carbanion mechanisms XVIII. Generation of silyl anions by nucleophilic cleavage of disilanes

DOI: 10.1016/0022-328X(92)83433-I

Source and publish data:

Journal of Organometallic Chemistry p. 85 - 89 (1992)

Update date:2022-08-04

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Authors:

Buncel, Erwin

Venkatachalam, T. Krishnan

Edlund, U.

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Article abstract of DOI:10.1016/0022-328X(92)83433-I

Organosilyl potassium compounds are conveniently generated by cleavage of hexaorganodisilanes with potassium t-butoxide in common solvents other than HMPA (i.e. in THF or DME).Nucleophilic attack on unsymmetrical disilanes results in formation of the more

Full text of DOI:10.1016/0022-328X(92)83433-I

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