Angewandte Chemie - International Edition in English p. 1723 - 1725 (1997)
Update date:2022-09-26
Topics:
Linde
Arnold
Norrby
Akermark
For the direct epoxidation of alkenes radical intermediates play no role. Instead investigations with the radical traps 1a-c indicate that manganaoxetane intermediates are present. Radicals can form from the latter, particularly in the case of sterically crowded oxetanes, by homolytic cleavage of the Mn-C bond.
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