HETARYLATION OF C-NUCLEOPHILES: A NEW COURSE FOR THE REACTION OF N-FLUOROPYRIDINIUM SALTS WITH CARBANIONS.

DOI: 10.1016/S0040-4039(00)88572-X

Source and publish data:

Tetrahedron Letters p. 7379 - 7382 (1990)

Update date:2022-07-30

Topics:

Authors:

Gakh, Andrei A.

Kiselyov, Alexander S.

Semenov, Victor V.

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Article abstract of DOI:10.1016/S0040-4039(00)88572-X

The N-fluoropyridinium tetrafluoroborate reactions with carbanions were found either to follow the cine -(tele)-AEa-substitution or go through possible formation of a carbenic (cationic) intermediate; as a result 2- or 4-pyridyl derivatives are formed.

Full text of DOI:10.1016/S0040-4039(00)88572-X

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