HETARYLATION OF C-NUCLEOPHILES: A NEW COURSE FOR THE REACTION OF N-FLUOROPYRIDINIUM SALTS WITH CARBANIONS.

DOI: 10.1016/S0040-4039(00)88572-X

Source and publish data:

Tetrahedron Letters p. 7379 - 7382 (1990)

Update date:2022-07-30

Topics:

Authors:

Gakh, Andrei A.

Kiselyov, Alexander S.

Semenov, Victor V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88572-X

The N-fluoropyridinium tetrafluoroborate reactions with carbanions were found either to follow the cine -(tele)-AEa-substitution or go through possible formation of a carbenic (cationic) intermediate; as a result 2- or 4-pyridyl derivatives are formed.

Full text of DOI:10.1016/S0040-4039(00)88572-X

Products guided by the article

Product name:α-ethoxycarbonyl-2-pyridineacetonitrile

Cas No:59601-57-9

R&D Labs maybe for 59601-57-9

Molobelamltrading

Contact:27-792-602929

Address:SIDNEY MUFAMADI STREET 009949 X44 0700 POLOKWANE,LIMPOPO
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
shanghai hekang chemical co.ltd

Contact:021-54173790

Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
Huludao Tianqi Shengye Chemical Co.,Ltd.

Contact:0086 429 2075777

Address:Area B,Shipbuilding Industry Park,Beigang District,Huludao City,Liaoning prov.,China

Relevant to this article

Efficient and facile three-component reaction for the synthesis of 2-amine-4,6-diarylpyrimidine under solvent-free conditions

Doi:10.1080/00397910802399932
(2009)
Doi:10.1021/jo00882a003
(1976)
Bromofluorination of olefins using BrF₃; an efficient route for fluoroalkenes and fluoroamines

Doi:10.1016/j.jfluchem.2006.04.008
(2006)
Reactions of tartaric acid with resorcinol

Doi:10.1002/ardp.19763090512
(1976)
Doi:10.1021/jf60212a065
(1977)
Doi:10.1016/S0040-4020(01)93796-2
(1976)

Article Doi