Chemistry of Heterocyclic Compounds p. 604 - 607 (1980)
Update date:2022-07-30
Topics:
Maksimova, T. N.
Mochalin, V. B.
Unkovskii, B. V.
N-Substituted 1,2,5,6-tetrahydropyridines are readily converted to the corresponding 1,2-diols by treatment with an aqueous solution of potassium permanganate in a neutral medium.The yields of the desired products depend on the character of the substituent attached to the nitrogen atom and decrease in the case of N-methyl-1,2,5,6-tetrahydropyridines as a consequence of the formation of side products formed as a result of more profound oxidation.The acylation of the synthesized diols was studied.The three-dimensional structures of the synthesized cis-diols were established by IR spectroscopy.
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