A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate

DOI: 10.1039/b401301h

Source and publish data:

Chemical Communications p. 1236 - 1237 (2004)

Update date:2022-07-29

Topics:

Authors:

Carcedo, Cristina

Dervisi, Athanasia

Fallis, Ian A.

Ooi, Liling

Abdul Malik

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Article abstract of DOI:10.1039/b401301h

The synthesis of the novel C₂-symmetric diphosphine 1,4:3,6-dianhydro-2,5-bis(diphenylphosphino)-D-mannitol (ddppm) from D-isomannide is reported and its performance in asymmetric hydrogenations discussed.

Full text of DOI:10.1039/b401301h

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