Journal of the American Chemical Society p. 1577 - 1583 (1980)
Update date:2022-08-03
Topics:
Soderquist, John A.
Hassner, Alfred
The preparation of 1-lithio derivatives of some conjugated vinyl ethers is described.Reaction of these compounds with the chlorotrimethyl derivatives of silicon, germanium, and tin gives the corresponding metallovinyl ethers in 50-80percent yield.At least in the case of silicon these reactions proceed with retention of stereochemistry.The silyl compounds undergo Z <*> E photoisomerization.Hydrolysis of the ethers in aqueous acetone gives the corresponding acylmetallanes in 60-75percent yield.The metalation and hydrolysis reactions are examined in some detail.The spectral properties of these novel unsaturated acylmetallanes are presented and discussed.
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Doi:10.1021/ja00524a025
(1980)Doi:10.1039/c5dt02264a
(2015)Doi:10.1021/ja00523a026
(1980)Doi:10.1021/jo01302a014
(1980)Doi:10.1007/BF00951892
(1980)Doi:10.1016/S0040-4039(01)92956-9
(1981)