SYNTHESIS OF 2-ACETAMIDO-5-AMINO-2,5-DIDEOXY-D-GLUCO- AND -L-IDO-PYRANOSE DERIVATIVES

Article abstract of DOI:10.1016/S0008-6215(00)85656-6

Methyl 2-acetamido-5,6-anhydro-2-deoxy-α-L-idofuranoside ( 6 ) was prepared from 2-acetamido-2-deoxy-D-glucose in six steps.Opening of the epoxide ring in the 3-(tetrahydropyran-2-yl) ether of 6 with aqueous sodium hydroxide gave methyl 2-acetamido-2-deox