Journal of Organic Chemistry p. 5405 - 5412 (2004)
Update date:2022-07-30
Topics:
Bastin, Stephanie
Eaves, Richard J.
Edwards, Christopher W.
Ichihara, Osamu
Whittaker, Mark
Wills, Martin
The appropriate combination of methacrylate polymers permits the synthesis of a soluble polymer for use in ruthenium(II)-catalyzed asymmetric transfer hydrogenation reactions. Using a 7:3 copolymer of a poly(ethylene glycol) ester and a hydroxyethyl ester, a derived ruthenium(II)/norephedrine complex catalyses reduction of acetophenone in up to 95% yield and 81% ee.
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