Journal of the Chemical Society. Perkin transactions I p. 263 - 269 (1981)
Update date:2022-08-05
Topics:
Bezuidenhoudt, Barend C. B.
Brandt, E. Vincent
Roux, David G.
The absolute configuration of (αR)-α,2'-dihydroxy-4,4'-dimethoxydihydrochalcone from the heartwood of Pterocarpus angolensis D.C. is established.Its structure is substantiated by synthesis and by photochemical conversion of its α-O-tosyl derivative into an α-tosyloxymethyldeoxybenzoin and hence to the α-methyldeoxybenzoin analogue.The photochemical step also leads, amongst others, to α-hydroxymethyldeoxybenzoin, β-hydroxydihydrochalcone, and 2-benzylbenzofuran-3-one analogues depending on the conditions the photolysis.
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Doi:10.1055/s-1981-29361
(1981)Doi:10.1016/0040-4020(80)80183-9
(1980)Doi:10.1021/ja00399a031
(1981)Doi:10.1002/chem.201500476
(2015)Doi:10.1016/S0031-9422(00)91141-5
(1974)Doi:10.1039/b812580e
(2009)
