Journal of the Chemical Society. Perkin transactions I p. 105 - 108 (1981)
Update date:2022-08-05
Topics:
Banthorpe, Derek V.
Christou, Paul N.
Artemiseole, an ether isolated from Artemisia tridentata, has been proved to be 1,4,4-trimethyl-6-vinyl-3-oxabicyclo<3.1.0>hexane by an unambiguous synthesis in six steps from 1-chloro-2-methylpropene, and is thus an irregular monoterpene of the santolinyl class.The availability of 3,6,6-trimethyl-5,6-dihydr-2H-pyran as an unexpected minor product of one of the steps allowed an efficient eight-step syntesis from the chloro-compound of (Z)-5-ethylidene-5,6-dihydro-3,6,6-trimethylpyran-2-one to be carried out: this is an irregular monoterpene lactone from Chrysanthemum flosculosum that had previously been prepared only by a fifteen-stage process.
View MoreJinzhou Jiutai Pharmaceutical Co.,Ltd
Contact:+86-0416-5179890
Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
Taizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Taizhou Crene Biotechnology co.ltd
Contact:86-576-88813233 88205808
Address:Economic Developed Zone of Taizhou Zhejiang China
website:http://www.easchem.com
Contact:+86-731-89722861 89722891
Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Dalian Join King Biochemical Tech. Co., Ltd.
Contact:0411 39216206
Address:814 First State Blvd
Doi:10.1021/ja00398a058
(1981)Doi:10.1021/jo00328a043
(1981)Doi:10.1016/0040-4039(81)80072-X
(1981)Doi:10.1039/P19810000887
(1981)Doi:10.1016/0223-5234(87)90289-3
(1987)Doi:10.1021/ol070527h
(2007)
