Ruthenium-catalyzed alkoxylation of a hydrodisilane without Si[sbnd]Si bond cleavage

DOI: 10.1016/j.tetlet.2016.11.073

Source and publish data:

Tetrahedron Letters p. 9 - 12 (2017)

Update date:2022-09-26

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Authors:

Kanno, Ken-ichiro

Aikawa, Yumi

Kyushin, Soichiro

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Article abstract of DOI:10.1016/j.tetlet.2016.11.073

Transition metal-catalyzed synthesis of alkoxydisilanes via dehydrogenative coupling of a hydrodisilane with alcohols is reported. During the reaction, the Si[sbnd]Si bond is preserved effectively when [RuCl₂(p-cymene)]₂is used as a catalyst. Various alcohols can be used in this alkoxylation.

Full text of DOI:10.1016/j.tetlet.2016.11.073

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