Highly Regioselective Reduction of Ring B Seco-5α-steroid Anhydrides to afford the Lactone Grouping Characteristic of Brassinolide

DOI: 10.1039/c39820000943

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 943 - 944 (1982)

Update date:2022-09-26

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Authors:

Brooks, Charles J. W.

Ekhato, I. Victor

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Article abstract of DOI:10.1039/c39820000943

B-Homo-7-oxa-5α-cholestan-6-ones are formed in high yield via sodium borohydride reduction of the corresponding cyclic anhydrides.

Full text of DOI:10.1039/c39820000943

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