STEREOSELECTIVE ACYCLIC SYNTHESIS VIA ALLYLMETALS: STRUCTURAL DEPENDENCE IN A LEWIS-ACID CATALYZED ADDITION OF ALLYLTINS TO ALDEHYDES

DOI: 10.1246/cl.1982.1299

Source and publish data:

Chemistry Letters p. 1299 - 1302 (1982)

Update date:2022-08-05

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Authors:

Koreeda, Masato

Tanaka, Yoshio

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Article abstract of DOI:10.1246/cl.1982.1299

Lewis-acid catalyzed reaction of allyltins with aldehydes at -78 deg C provide homoallyl alcohols with high stereoselectivity; 2-alkenyltins in general provide erythro adducts preferentially with an erithro/threo ratio greater than 12/1, whereas only thre

Full text of DOI:10.1246/cl.1982.1299

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