Generation and Reactivities of Organocerium Reagents

DOI: 10.1039/c39820001042

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1042 - 1044 (1982)

Update date:2022-09-26

Topics:

Authors:

Imamoto, Tsuneo

Kusumoto, Tetsuo

Yokoyama, Masataka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820001042

Organocerium reagents, prepared in situ by the treatment of organolithium compounds with cerium(III) iodide, exhibit characteristic reactivities toward ketones; at -65 deg C, nucleophilic additions give the corresponding tertiary alcohols in excellent yields; while, at 0 deg C to ca. room temperature, reductive coupling and/or reduction of the ketones prevail.

Full text of DOI:10.1039/c39820001042

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzenemethanol, a-butyl-4-iodo-a-methyl-

Cas No:84735-52-4

R&D Labs maybe for 84735-52-4

JIN TAN CHENG'EN CHEMICAL CO.,LTD.

Contact:86-519-82116250

Address:NO.102，village Dongfang，conomic development zone
Wuhan Biet Co., Ltd

website:http://www.biet.com.cn/

Contact:+86-27-8369 8488

Address:No. 6, Building 21, China Merchants Fanwang, Sixin North Road, Hanyang District, Wuhan City, Hubei Province
Changzhou Kingyo Chemical Corporation Ltd.

website:http://www.kingyochem.com

Contact:+86-519-85105717

Address:19# Wuqing North Road, Changzhou , Jiangsu, China
Shreeji pharma international

Contact:0091-265-2313036

Address:311, ATLANTIS HEIGHTS SARABHAI MAIN ROAD,VADIWADI ,VADODARA
Wuhan Better Organic Technology Inc.

Contact:13307163183

Address:Wuhan Economic&Technology Development Zone, Hubei

Relevant to this article

Primary and secondary allyltitanium(IV) reagents in aldehyde allylation II: Application to an enantioselective preparation of a C1-C7 fragment of spiramycin

Doi:10.1055/s-2004-834913
(2005)
Synthesis and transformations of alkyl N-(1-cyclohex-3-enyl)carbamates prepared from cyclohex-3-ene carboxylic acid via Curtius rearrangement

Doi:10.1016/j.tet.2004.11.037
(2005)
Crystallization-Induced Dynamic Resolution toward the Synthesis of (S)-7-Amino-5H,7H-dibenzo[b,d]-azepin-6-one: An Important Scaffold for γ-Secretase Inhibitors

Doi:10.1021/acs.oprd.6b00207
(2016)
Cyanine dyes, new potent antitumor agents

Doi:10.1248/cpb.30.3106
(1982)
Pyrazolo[1,5-a]pyrimidines, triazolo[1,5-a]pyrimidines and their tricyclic derivatives as corticotropin-releasing factor 1 (CRF₁) receptor antagonists

Doi:10.1016/j.bmc.2011.08.055
(2011)
PENTAFLUOROPHENYL DERIVATIVES OF PALLADIUM(II) AND PLATINUM(II) WITH O-DONOR LIGANDS

Doi:10.1016/S0022-328X(00)98514-0
(1983)

Article Doi