Journal of the Chemical Society. Chemical communications p. 1042 - 1044 (1982)
Update date:2022-09-26
Topics:
Imamoto, Tsuneo
Kusumoto, Tetsuo
Yokoyama, Masataka
Organocerium reagents, prepared in situ by the treatment of organolithium compounds with cerium(III) iodide, exhibit characteristic reactivities toward ketones; at -65 deg C, nucleophilic additions give the corresponding tertiary alcohols in excellent yields; while, at 0 deg C to ca. room temperature, reductive coupling and/or reduction of the ketones prevail.
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(1983)
