ADDITION OF FUNCTIONALIZED ORGANOLITHIUM REAGENTS TO p-BENZOQUINONES AND CYCLOHEXADIENONES: SYNTHESIS OF FUNCTIONALIZED CYCLOHEXADIENONES, DIENOLS AND DIENEDIOLS

DOI: 10.1016/S0040-4039(00)81347-7

Source and publish data:

Tetrahedron Letters p. 131 - 134 (1983)

Update date:2022-09-26

Topics:

Authors:

Fischer, Alfred

Henderson, George Narayanan

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Article abstract of DOI:10.1016/S0040-4039(00)81347-7

Low temperature addition of functionalized alkyllithium reagents to p-benzoquinones produces 4-alkyl-4-hydroxycyclohexa-2,5-dienones, and reaction of excess of the reagents with quinones yields 1,4-dialkylcyclohexa-2,5-diene-1,4-diols.With 4-acetoxy-, 4-h

Full text of DOI:10.1016/S0040-4039(00)81347-7

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