Journal of the Chemical Society. Perkin transactions I p. 2059 - 2064 (1983)
Update date:2022-08-05
Topics:
Hutchins, Michael
Sainsbury, Malcolm
Scopes, David I. C.
Photolysis of N-amino- and N-nitroso-derivatives of 1,2,3,4-tetrahydropapaverine fails to produce aryl-aryl coupled products analogous to O-methylflavinantine.Instead both the 1- and 2-substituents of the heterocyclic ring are cleaved to give 6,7-dimethoxy-3,4-dihydroisoquinolines and veratraldehyde, the latter being an oxidation product of the 3,4-dimethoxybenzyl radical and/or cation.From this evidence, and the results of an electrolysis experiment carried out at high dilution, it is considered that the anodic cyclisation of laudanosine to O-methylflavinantine proceeds through homogeneous electron transfer rather than via homoconjugative activation within the intermediate radical cation as proposed by other workers.
View MoreContact:86-21-50966856
Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Changzhou Anyi Biochem Co., Ltd.(expird)
Contact:+86-519-88836158
Address:no,51 caoda
Zhengzhou Institute of Chiral Pharmer Research Co., Ltd.
Contact:86-371-55219111
Address:15 Floor, 2 Building, Central China Technovalley, Zhongyuan West Road
SHANDONG AONA CHEMICAL CO.,LTD.
Contact:86-532-85762926
Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.
Contact:--
Address:80G, No.1 Building, Guodu Development Mansion, No. 182 Zhaohui Road, Hangzhou City, Zhejiang Province,China.
Doi:10.1016/j.tetlet.2018.05.028
(2018)Doi:10.1021/jm980374r
(1998)Doi:10.1016/0022-328X(84)80322-8
(1984)Doi:10.1016/j.bmcl.2006.01.005
(2006)Doi:10.1016/j.jorganchem.2006.04.018
(2006)Doi:10.1021/ja0602997
(2006)
