Stereoselective synthesis of (E)-ArCF=CFR and (E)-ArCH=CFR from ArCH(OH)CFBr2

DOI: 10.1016/0040-4039(95)01257-I

Source and publish data:

Tetrahedron Letters p. 6271 - 6274 (1995)

Update date:2022-07-29

Topics:

Authors:

Kuroboshi, Manabu

Yamada, Nobuko

Takebe, Yoko

Hiyama, Tamejiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)01257-I

(E)-vic-Difluoro olefin, RCF=CFBr, was synthesized by dehydrobromination of RCFHCFBr₂ using lithium 2,2,6,6-tetramethylpiperidide. (E)-Fluoro olefin, RCH=CFBr, was obtained by treatment of RCH(OAc)CFBr₂ with EtMgBr and HN(i-Pr)₂.

Full text of DOI:10.1016/0040-4039(95)01257-I

Products guided by the article

Product name:Benzonitrile, 4-(2-bromo-2-fluoroethenyl)-

Cas No:897393-09-8

R&D Labs maybe for 897393-09-8

Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
Suzhou Howsine Biological Technology Co.,Ltd(expird)

website:http://www.howsine.com

Contact:86-512-67262751

Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Suzhou Time-chem Technologies Co., Ltd.

Contact:0512-63983931/68086856

Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.

Contact:0086-0576-88551200,88886292 ,88880039

Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China

Relevant to this article

Moderating the nucleophilicity of the sulfide ligands in the dinuclear {Pt₂S₂} metalloligand system using triphenylarsine

Doi:10.1016/j.jorganchem.2006.02.020
(2006)
Fluorous synthesis of hydantoin-, piperazinedione-, and benzodiazepinedione-fused tricyclic and tetracyclic ring systems

Doi:10.1002/ejoc.200600077
(2006)
The synthesis of 1,4-ethano-1,2,3,4-tetrahydroisoquinolines as rigid analogues of adrenergic agents

Doi:10.1002/jhet.5570200629
(1983)
A highly selective fluorogenic substrate for imaging glutathione S-transferase P1: Development and cellular applicability in epigenetic studies

Doi:10.1039/c9cc03064f
(2019)
A novel ultrasound-sensitive mechanofluorochromic AIE-compound with remarkable blue-shifting and enhanced emission

Doi:10.1039/c4tc00553h
(2014)
Design, synthesis and biological evaluation of 1-hydroxy-2-phenyl-4-pyridyl-1H-imidazole derivatives as xanthine oxidase inhibitors

Doi:10.1016/j.ejmech.2018.01.060
(2018)

Article Doi