Construction of tricyclic enone, a common precursor for aphidicolane and stemodane B/C/D-ring system

DOI: 10.1248/cpb.54.1138

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1138 - 1143 (2006)

Update date:2022-08-06

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Authors:

Tanaka, Tetsuaki

Yamamoto, Sachiko

Hiramatsu, Kei

Murakami, Kazuo

Yoshino, Hitoshi

Patra, Debasis

Iwata, Chuzo

Ohno, Hiroaki

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Article abstract of DOI:10.1248/cpb.54.1138

Synthesis of a tricyclic enone (B/C/D ring system), a common key precursor for the aphidicolane- and stemodane-type diterpene, is described. The key reaction for the construction of the quaternary carbon center is allylation of epoxide at the more substit

Full text of DOI:10.1248/cpb.54.1138

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