Tetrahedron p. 2441 - 2449 (1984)
Update date:2022-07-30
Topics:
Barbarella, G.
Brueckner, S.
Pitacco, G.
Valentin, E.
The title heterocycles rearrange into a mixture of diastereomeric hexahydro-1(H)-pentalenone derivatives, which undergo nucleophilic eliminative ring fission by methanol to give 1-amino-2-nitroalkylated cyclopentancarboxylic esters.The X-ray structure determination of hexahydro-2-methyl-2-nitro-3-phenyl-6a-(1-piperidinyl)-1(2H)-pentalenone <2S-(2α,3α,3aα,6aα)> is also reported.
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Doi:10.1039/b616423d
(2007)Doi:10.1135/cccc19841722
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(1964)
