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UV ABSORBER MC80
Cas No: 5466-77-3
No Data 1 Kilogram 10000 Kilogram/Day Qingdao Jade New Material Technology CO.,Ltd Contact Supplier
Octyl Methoxycinnamate
Cas No: 5466-77-3
USD $ 480.0-500.0 / Metric Ton 1 Metric Ton 50-100 Metric Ton/Day Hangzhou Weck Chemical Industry Co., Ltd. Contact Supplier
Octyl 4-methoxycinnamate
Cas No: 5466-77-3
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Octyl P-Methoxycinnamate supplier in China
Cas No: 5466-77-3
No Data No Data Metric Ton/Day Simagchem Corporation Contact Supplier
Octyl 4-methoxycinnamate
Cas No: 5466-77-3
USD $ 1.0-3.0 / Kilogram 1 Kilogram 10 Kilogram/Day Hebei yanxi chemical co.,LTD. Contact Supplier
Octyl 4-methoxycinnamate
Cas No: 5466-77-3
No Data 1 Kilogram 5000 Metric Ton/Year Hefei TNJ chemical industry co.,ltd Contact Supplier
2-Ethylhexyl 4-MethoxycinnaMate
Cas No: 5466-77-3
No Data 1 Gram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
2-Ethylhexyl Trans-4-Methoxycinnamate
Cas No: 5466-77-3
No Data 5 Milligram Gram/Day Chengdu Lemeitian Pharmaceutical Technology Co,. Ltd Contact Supplier
2-Ethylhexyl 4-MethoxycinnaMate Liquid Octyl 4-methoxycinnamate
Cas No: 5466-77-3
USD $ 70.0-70.0 / Kilogram 1 Kilogram 10 Metric Ton/Month Shaanxi Greenyo Biotech Co., Ltd. Contact Supplier
UV absorber MC80
Cas No: 5466-77-3
No Data 25 Kilogram 100 Kilogram/Month Qingdao Truelight Functional Material Technolgy Co.,Ltd Contact Supplier

5466-77-3 Usage

Chemical Properties

colourless or pale yellow liquid

Uses

2-Ethylhexyl 4-Methoxycinnamate is an UV induced cyclobutane pyrimidine dimer (CDP) formation inhibitior.

Fire Hazard

Flash point data for Octyl 4-methoxycinnamate are not available, however, Octyl 4-methoxycinnamate is probably combustible.

Air & Water Reactions

Insoluble in water.

General Description

Colorless to pale yellow viscous liquid.

Brand name

Parsol (Roche); Neo Heliopan (H & R Florasynth); Escalol (ISP Van Dyk) Note—The International Cosmetic Ingredient (INCI) name for octinoxate is octyl methoxycinnamate.
InChI:InChI=1/C18H26O3/c1-4-6-7-8-16(5-2)21-18(19)14-11-15-9-12-17(20-3)13-10-15/h9-14,16H,4-8H2,1-3H3/b14-11+

5466-77-3 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
USP (1477900)  Octinoxate  United States Pharmacopeia (USP) Reference Standard 5466-77-3 1477900-500MG 4,662.45CNY Detail
Sigma-Aldrich (PHR1080)  Octinoxate  pharmaceutical secondary standard; traceable to USP 5466-77-3 PHR1080-10G 4,312.04CNY Detail
Sigma-Aldrich (PHR1080)  Octinoxate  pharmaceutical secondary standard; traceable to USP 5466-77-3 PHR1080-1G 732.19CNY Detail
Sigma-Aldrich (55529)  2-Ethylhexyl 4-methoxycinnamate  analytical standard 5466-77-3 55529-100MG 850.59CNY Detail
TCI America (M1082)  2-Ethylhexyl 4-Methoxycinnamate  >97.0%(GC) 5466-77-3 500mL 1,780.00CNY Detail
TCI America (M1082)  2-Ethylhexyl 4-Methoxycinnamate  >97.0%(GC) 5466-77-3 100mL 596.00CNY Detail
TCI America (M1082)  2-Ethylhexyl 4-Methoxycinnamate  >97.0%(GC) 5466-77-3 25mL 248.00CNY Detail

5466-77-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Octyl 4-methoxycinnamate

1.2 Other means of identification

Product number -
Other names 2-ethylhexyl (E)-3-(4-methoxyphenyl)prop-2-enoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5466-77-3 SDS

5466-77-3Synthetic route

diazo-acetic acid-(2-ethyl-hexyl ester)

diazo-acetic acid-(2-ethyl-hexyl ester)

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With Fe(TCP)Cl; polyethylene supported arsine; polymethylhydrosiloxane In toluene at 110℃; for 20h; Wittig type reaction; Inert atmosphere; stereoselective reaction;98%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tetrabutylammomium bromide; C32H26Cl2N8O4Pd2; potassium carbonate In methanol; water for 0.416667h; Reflux;97%
With C43H54NO5P; palladium diacetate; triethylamine In water at 40℃; for 12h; Heck Reaction;95%
With tributyl-amine; chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium In 1-methyl-pyrrolidin-2-one at 140℃; for 15h; Heck Reaction; Inert atmosphere;94%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-methoxybenzenediazonium tetrafluoroborate
459-64-3

4-methoxybenzenediazonium tetrafluoroborate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
[(1,3-dimesitylimidazol-2-ylidene)(benzoquinone)Pd(0)]2 In methanol at 50℃; for 1h; Heck reaction;96%
With calcium carbonate; Lindlar's catalyst In methanol93%
(IMes)Pd(NQ) In ethanol at 50℃; for 1h; Conversion of starting material; Heck Reaction;88%
palladium on activated carbon In dichloromethane; water; dimethyl sulfoxide80%
With xonotlite; palladium diacetate In methanol at 20℃; Reagent/catalyst;73%
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
24393-56-4

ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With toluene-4-sulfonic acid Heating;94%
tert-Octylamine
107-45-9

tert-Octylamine

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With acetic acid; palladium on charcoal92%
palladium of charcoal

palladium of charcoal

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With triethylamine In water; toluene92%
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

acetic acid methyl ester
79-20-9

acetic acid methyl ester

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

A

2-ethylhexyl acetate
103-09-3

2-ethylhexyl acetate

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Stage #1: 2-Ethylhexyl alcohol; acetic acid methyl ester; 4-methoxy-benzaldehyde With sodium methylate at 20 - 100℃; under 45.0045 Torr; for 3.33333h;
Stage #2: With sulfuric acid; toluene-4-sulfonic acid In water at 100℃; for 0.25h;
A n/a
B 91.5%
Stage #1: 2-Ethylhexyl alcohol; acetic acid methyl ester; 4-methoxy-benzaldehyde With sodium methylate at 20 - 100℃; under 45.0045 Torr; for 3.33333h;
Stage #2: With sulfuric acid In water at 100 - 150℃; for 2.25h;
A n/a
B 90%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With Hoveyda-Grubbs catalyst first generation In 1,2-dichloro-ethane at 70℃; Cross Metathesis; Schlenk technique; Inert atmosphere; Glovebox;89%
With Hoveyda-Grubbs catalyst second generation In toluene at 70℃; for 6h; Inert atmosphere; Glovebox;> 99 %Spectr.
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In 1,2-dichloro-ethane at 70℃; for 4h; Solvent; Reagent/catalyst; Inert atmosphere; Glovebox;
With 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; 2,6-di-tert-butyl-4-methyl-phenol In toluene at 70℃; for 1.5h; Catalytic behavior; Inert atmosphere; Schlenk technique;86 %Chromat.
2-ethyl-1,3-hexane diol
94-96-2

2-ethyl-1,3-hexane diol

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

ethylene glycol
107-21-1

ethylene glycol

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; triphenylphosphine; palladium diacetate In 1-bromo-4-methoxy-benzene88%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

para-iodoanisole
696-62-8

para-iodoanisole

diethylamine
109-89-7

diethylamine

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With acetic acid; palladium on charcoal86.6%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

1-(benzoyl)piperidine-2,6-dione

1-(benzoyl)piperidine-2,6-dione

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With lithium bromide; palladium dichloride In 1-methyl-pyrrolidin-2-one at 160℃; for 15h; Heck Reaction; Inert atmosphere; chemoselective reaction;84.8%
5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione
15795-54-7

5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Stage #1: 5-(4-methoxybenzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione; 2-Ethylhexyl alcohol With iron(III) chloride hexahydrate In nitromethane for 0.25h; Microwave irradiation;
Stage #2: With piperidine In nitromethane for 0.25h; Microwave irradiation; stereoselective reaction;
84%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine; Cy2NMe2 In 1,4-dioxane at 20℃; for 148h; Heck coupling;83%
With C21H21ClN4Pd; triethylamine In 1-methyl-pyrrolidin-2-one at 140℃; for 8h;73%
With sodium acetate; *6Ph4PCl In various solvent(s) at 130℃;71%
With tri-n-propylamine In 1-methyl-pyrrolidin-2-one at 175℃; for 24h; Heck reaction; Inert atmosphere;34%
With dimethylaminoacetic acid; bis(benzonitrile)palladium(II) dichloride
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With potassium phosphate; catacxium A; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 120℃; for 24h; Substitution; Heck reaction;82%
methanolic sodium methylate

methanolic sodium methylate

boron trifluoride dimethyl etherate
353-42-4

boron trifluoride dimethyl etherate

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

p-Anisaldehyde dimethyl acetal
2186-92-7

p-Anisaldehyde dimethyl acetal

methyl 3-(4-methoxyphenyl)-3-methoxypropanoate
69098-08-4

methyl 3-(4-methoxyphenyl)-3-methoxypropanoate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
75%
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; p-cresol In dichloromethane for 2h; Reflux; Inert atmosphere;A 53%
B 47%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In 1,2-dichloro-ethane at 70℃; for 4h; Reagent/catalyst; Inert atmosphere; Glovebox;
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
40%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

α-hydrazino-phenylacetic acid

α-hydrazino-phenylacetic acid

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 99 percent / 4-(dimethylamino)pyridine / dimethylformamide / 25 °C
2: 94 percent / p-TsOH / Heating
View Scheme
Multi-step reaction with 2 steps
1: 97 percent / 4-(dimethylamino)pyridine; acetic acid; piperidine / dimethylformamide / 10 - 25 °C
2: 94 percent / p-TsOH / Heating
View Scheme
conc. H2 SO4

conc. H2 SO4

n-Amyl nitrite
463-04-7

n-Amyl nitrite

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
palladium diacetate In 2-Ethylhexyl alcohol
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

A

sodium bromide

sodium bromide

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; triphenylphosphine; palladium diacetate In 1-bromo-4-methoxy-benzene
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

Aliquat 336
5137-55-3

Aliquat 336

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; triphenylphosphine; palladium diacetate
MTB ether

MTB ether

2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With sodium carbonate; palladium diacetate
Estragole
140-67-0

Estragole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) / toluene / 0.25 h / 40 °C / Inert atmosphere; Glovebox
2: Hoveyda-Grubbs catalyst second generation / toluene / 6 h / 70 °C / Inert atmosphere; Glovebox
View Scheme
Multi-step reaction with 2 steps
1: [CpRu(PN)(MeCN)]PF6 / toluene / 0.5 h / 40 °C / Inert atmosphere; Glovebox
2: Hoveyda-Grubbs catalyst second generation / toluene / 6 h / 70 °C / Inert atmosphere; Glovebox
View Scheme
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

A

4-Methoxystyrene
637-69-4

4-Methoxystyrene

B

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In 1,2-dichloro-ethane at 70℃; for 1h; Inert atmosphere; Glovebox;
2-Ethylhexyl acrylate
103-11-7

2-Ethylhexyl acrylate

E-1-(4'-methoxyphenyl)prop-1-ene
4180-23-8

E-1-(4'-methoxyphenyl)prop-1-ene

A

4-Methoxystyrene
637-69-4

4-Methoxystyrene

C

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 70℃; for 4h; Reagent/catalyst; Inert atmosphere; Glovebox;
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

3-(4-methoxy-phenyl)-propionic acid 2-ethyl-hexyl ester
127794-13-2

3-(4-methoxy-phenyl)-propionic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
With Triethoxysilane; water; palladium diacetate In tetrahydrofuran Ambient temperature;92%
5-methyl-1,3-benzodioxole
7145-99-5

5-methyl-1,3-benzodioxole

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

2'-ethylhexyl 3-(2-methyl-4,5-methylenedioxyphenyl)-3-(4-methoxyphenyl)propionate

2'-ethylhexyl 3-(2-methyl-4,5-methylenedioxyphenyl)-3-(4-methoxyphenyl)propionate

Conditions
ConditionsYield
With palladium diacetate; trifluoroacetic acid In dichloromethane at 20℃; for 10h; Hydroarylation;86%
With trifluoroacetic acid; palladium diacetate In dichloromethane at 20℃; for 10h; hydroarylation;85%
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

1,4-dimethoxybezene
150-78-7

1,4-dimethoxybezene

2'-ethylhexyl 3-(2,5-dimethoxyphenyl)-3-(4-methoxyphenyl)propionate

2'-ethylhexyl 3-(2,5-dimethoxyphenyl)-3-(4-methoxyphenyl)propionate

Conditions
ConditionsYield
With palladium diacetate; trifluoroacetic acid In dichloromethane at 20℃; for 10h; Hydroarylation;83%
1,2,3-trimethoxybenzene
621-23-8

1,2,3-trimethoxybenzene

2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

2'-ethylhexyl 3-(2,4,6-trimethoxyphenyl)-3-(4-methoxyphenyl)propionate

2'-ethylhexyl 3-(2,4,6-trimethoxyphenyl)-3-(4-methoxyphenyl)propionate

Conditions
ConditionsYield
With palladium diacetate; trifluoroacetic acid In dichloromethane at 20℃; for 10h; Hydroarylation;65%
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

A

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene
1619923-81-7

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

B

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

C

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: diisobutylaluminium hydride / hexane / 2 h / 0 °C
2.1: dipyridinium dichromate; aluminum oxide / dichloromethane / 24 h / 20 °C
3.1: L-proline; acetic acid / methanol; acetonitrile / 5 h / 20 °C
3.2: 1 h / 20 °C
View Scheme
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

A

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene
1619923-81-7

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

B

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

2-hydroxymethyl-3-(p-methoxyphenyl)-1-phenylamino-1,2,3,4-tetrahydronaphthalene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: diisobutylaluminium hydride / hexane / 2 h / 0 °C
2.1: dipyridinium dichromate; aluminum oxide / dichloromethane / 24 h / 20 °C
3.1: L-proline; acetic acid / methanol; acetonitrile / 5 h / 20 °C
3.2: 1 h / 20 °C
View Scheme
2-ethylhexyl methoxycinnamate
5466-77-3

2-ethylhexyl methoxycinnamate

A

C24H23NO2
1619923-76-0

C24H23NO2

B

C24H23NO2

C24H23NO2

C

C24H23NO2

C24H23NO2

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: diisobutylaluminium hydride / hexane / 2 h / 0 °C
2: dipyridinium dichromate; aluminum oxide / dichloromethane / 24 h / 20 °C
3: L-proline; acetic acid / methanol; acetonitrile / 5 h / 20 °C
View Scheme

5466-77-3Upstream product

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