THE STEREOCHEMICALLY CONTROLLED HORNER-WITTIG ROUTE TO UNSATURATED ACIDS: THE BAEYER-VILLIGER REARRANGEMENT OF α-(1-Ph2PO-ALKYL)-CYCLOHEXANONES

DOI: 10.1016/S0040-4039(00)84504-9

Source and publish data:

Tetrahedron Letters p. 2265 - 2266 (1986)

Update date:2022-08-03

Topics: Oxidation Ester Lactone Ketone Alkene carbonyl compound Stereoisomer Cyclohexanone Horner-Wittig reaction Unsaturated acids Phosphonium ylide

Authors:

Levin, Daniel

Warren, Stuart

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Article abstract of DOI:10.1016/S0040-4039(00)84504-9

Lithiated alkyl diphenylphosphine oxides attack cyclic epoxides with high stereoselectivity: Baeyer-Villiger rearrangement of the derived ketones gives Horner-Wittig intermediates for the synthesis of Z unsaturated acids

Full text of DOI:10.1016/S0040-4039(00)84504-9

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