SPECTRA, FORMATION CONSTANTS, REACTIONS AND CATALYTIC ACTIVITIES OF NITROGEN-BONDED UNSATURATED NITRILE COMPLEXES OF RHODIUM(I)

Article abstract of DOI:10.1016/0022-328X(85)80153-4

Cationic rhodium(I) complexes, ClO4 (L = CH2=C(CH3)CN, cis-CH3CH=CHCN, trans-CH3CH=CHCN, CH2=CHCH2CN; PPh3 = P(C6H5)3) have been prepared by the reactions of Rh(ClO4)(CO)(PPh3)2 with L.Spectral data suggest that L is coordinated to rhodium