SPECTRA, FORMATION CONSTANTS, REACTIONS AND CATALYTIC ACTIVITIES OF NITROGEN-BONDED UNSATURATED NITRILE COMPLEXES OF RHODIUM(I)

DOI: 10.1016/0022-328X(85)80153-4

Source and publish data:

Journal of Organometallic Chemistry p. 115 - 124 (1985)

Update date:2022-07-31

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Authors:

Lee, Myoung Kie

Kim, In Bum

Chin, Chong Shik

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Article abstract of DOI:10.1016/0022-328X(85)80153-4

Cationic rhodium(I) complexes, ClO4 (L = CH2=C(CH3)CN, cis-CH3CH=CHCN, trans-CH3CH=CHCN, CH2=CHCH2CN; PPh3 = P(C6H5)3) have been prepared by the reactions of Rh(ClO4)(CO)(PPh3)2 with L.Spectral data suggest that L is coordinated to rhodium

Full text of DOI:10.1016/0022-328X(85)80153-4

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Product name:Rh(CH₂CHCH₂CN)(CO)(P(C₆H₅)3)2⁽¹⁺⁾*ClO₄^(1-)={Rh(CH₂CHCH₂CN)(CO)(P(C₆H₅)3)2}(ClO₄)

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