Bulletin of the Chemical Society of Japan p. 2424 - 2426 (1989)
Update date:2022-08-17
Topics:
Hashiba, Shigeto
Fuchigami, Toshio
Tsutomu, Nonaka
A stoichiometry for the reductive dehalogenation of an organic halide with carbonylferrates was established: One mol of the halide was quantitatively reduced with the carbonylferrates derived from 0.2 mol of pentacarbonyl iron(0) and 2 mol of cathodically-generated tetramethylammonium methoxide.The dehalogenation was also examined using a variety of halides under the stoichiometric reaction conditions.
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