Angewandte Chemie International Edition
10.1002/anie.201805372
COMMUNICATION
S 2
mixture of both isomers) and (B) further Au catalysed reactions with Y PCy
1
F
4
(
S 2
H NMR yields; [Au] = Y PCy ∙AuCl, NaBAr ).
Acknowledgements
This work was supported by the European Research Council
Starting-Grant: YlideLigands 677749) and the German Research
(
Foundation within the Cluster of Excellence RESOLV EXC1069.
Keywords: Ylides • Phosphine ligands • Catalysis • Structure
elucidation • Carbanion
Figure 5. (A) Hydroamination of different alkynes with different amines ([a] 1:1
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