Chemical and Pharmaceutical Bulletin p. 133 - 135 (1999)
Update date:2022-08-22
Topics:
Itoh, Takashi
Matsuya, Yuji
Maeta, Hiromi
Miyazaki, Michiko
Nagata, Kazuhiro
Ohsawa, Akio
Secondary amines were allowed to react with nitric oxide in the presence of oxygen to afford N-nitrosamines in good yields. Detailed investigation revealed that the reaction proceeded by two pathways; the one involves the catalytic behavior of oxygen, and the other consumes a stoichiometrical amount of oxygen. Both pathways afforded the same nitroso adducts.
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