A. Mohammadinezhad, B. Akhlaghinia
22. MacQueen PM, Tassone JP, Diaz C, Stradiotto M (2018) J Am
Chem Soc 140:5023
naphthols, benzylic, allylic, and aliphatic alcohols gave the
corresponding products under mild reaction conditions.
The present heterogeneous nanostructured catalyst expands
the scope of the substrate by reducing reaction time and
temperature to avoid using palladium (due to its high cost
and toxicity) and copper(I) catalysts (due to its instability).
Furthermore, Fe3O4@AMCA-MIL53(Al)-NH2-CoII NPs can
be simply separated magnetically from the reaction mixture
and reused at least seven times with trace cobalt leaching
without a signifcant reduction in the yields of the desired
products. Moreover, the spectroscopic and microscopic stud-
ies of the 7th reused catalyst displayed considerable stability
of the Fe3O4@AMCA-MIL53(Al)-NH2-CoII NPs under the
reaction conditions. Afording good to excellent yields of
the C–O cross-coupled products without the need for any
special conditions underlines the potential of using cobalt as
a readily available, low-cost, non-toxic, and efcient catalyst
for C–O as well as C–C cross-coupling reactions. Further
studies are underway in our laboratory to extend this nano-
structured catalyst to other cross-coupling reactions.
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Guo X (2013) Dalton Trans 42:13698
Acknowledgements The authors gratefully acknowledge the partial
support of this study by Ferdowsi University of Mashhad Research
Council (Grant no. p/3/43367).
40. Alqadami AA, Naushad Mu, Alothman ZA, Ghfar AA (2017)
ACS Appl Mater Interfaces 9:36026
Compliance with Ethical Standards
41. Yaghi OM, O’Keefe M, Ockwig NW, Chae HK, Eddaoudi M,
Kim J (2003) Nature 423:705
Conflict of interest There is no confict of interest for each contribut-
ing author.
42. Jin M, Mou ZL, Zhang RL, Liang SS, Zhang ZQ (2017) Biosens
Bioelectron 91:162
43. Cohen SM (2012) Chem Rev 112:970
44. Stock N, Biswas S (2012) Chem Rev 112:933
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Y, Matsuo A, Kobayashi M, Chang HC, Ozawa TC, Suzuki M,
Sakata M, Takata M (2002) Science 298:2358
46. Ferey G, Cheetham AK (1999) Science 283:1125
47. Lu G, Li S, Guo Z, Farha OK, Hauser BG, Qi X, Wang Y, Wang
X, Han S, Liu X, DuChene JS, Zhang H, Zhang Q, Chen X, Ma
J, Loo SCJ, Wei WD, Yang Y, Hupp J, Huo F (2012) Nat Chem
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