N. Mukherjee, T. Chatterjee, B. C. Ranu
FULL PAPER
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J = 4.5 Hz, 4 H), 3.86 (t, J = 4.5 Hz, 4 H), 6.83 (d, J = 9.5 Hz, 2
H), 8.14 (d, J = 9.5 Hz, 2 H) ppm. 13C NMR (CDCl3, 100 MHz): δ
= 47.3 (2 C), 66.5 (2 C), 112.8 (2 C), 126.0 (2 C), 139.3, 155.1 ppm.
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2-(Piperidin-1-yl)pyridine: Table 2, entry 10. Pale yellow liquid
(134 mg, 83%). 1H NMR (CDCl3, 500 MHz): δ = 1.64 (s, 1 H),
3.52 (s, 4 H), 6.54–6.56 (m, 1 H), 6.64 (d, J = 8.5 Hz, 1 H), 7.42–
7.46 (m, 1 H), 8.16 (d, J = 5 Hz, 1 H) ppm. 13C NMR (CDCl3,
125 MHz): δ = 24.6, 25.5 (2 C), 46.4 (2 C), 107.3, 112.3, 137.5,
147.5, 159.4 ppm.
2-(Piperidin-1-yl)pyridine-3-carbonitrile: Table 2, entry 11. Yellow
1
liquid (172 mg, 92%). H NMR (CDCl3, 500 MHz): δ = 1.67 (s, 6
H), 3.64 (d, J = 5.5 Hz, 1 H), 6.64–6.67 (m, 1 H), 7.70–7.72 (m, 1
H), 8.28–8.29 (m, 1 H) ppm. 13C NMR (CDCl3, 125 MHz): δ =
24.5, 25.9 (2 C), 49.4 (2 C), 94.4, 113.2, 118.4, 143.9, 151.8,
160.9 ppm.
2-(1H-Imidazol-1-yl)pyrimidine: Table 2, entry 12. Yellow solid
1
(131 mg, 90%), m.p. 122–125 °C. H NMR (CDCl3, 500 MHz): δ
= 7.17–7.22 (m, 2 H), 7.89 (s, 1 H), 8.66–8.69 (m, 3 H) ppm. 13C
NMR (CDCl3, 125 MHz): δ = 116.7, 119.1, 130.3, 136.3, 158.9 (2
C), 174.8 ppm.
[8]
[9]
9-(4-Nitrophenyl)-9H-carbazole: Table 2, entry 13. Pale yellow solid
1
(239 mg, 83%), m.p. 207–209 °C. H NMR (CDCl3, 300 MHz): δ
= 7.16–7.29 (m, 2 H), 7.33–7.44 (m, 4 H), 7.69–7.72 (m, 2 H), 8.04–
8.10 (m, 2 H), 8.38–8.41 (m, 2 H) ppm. 13C NMR (CDCl3,
75 MHz): δ = 109.7, 120.4, 120.7, 121.3, 124.3, 125.0, 125.6, 126.6,
126.8, 139.9, 143.9 ppm.
Acknowledgments
The authors are pleased to acknowledge financial support from the
Department of Science and Technology (DST), New Delhi in the
form of the award of a J. C. Bose National Fellowship to B. C. R.
(grant number SR/S2/JCB-11/2008), and the Indian National Sci-
ence Academy, New Delhi for the award to B. C. R. of INSA Se-
nior Scientist. T. C. is grateful to the Council of Scientific and In-
dustrial Research (CSIR), New Delhi for his fellowship. The au-
thors thank the Nanoscience Project Unit at IACS, funded by DST,
New Delhi, for XPS analysis.
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