Tetrahedron Letters p. 995 - 996 (1986)
Update date:2022-08-23
Topics:
Isaacs, Neil S.
Abed, Obeid Hassan
Volumes of activation have been obtained from rate measurements between 1 and 1000 bar of reactions between triphenyl-p-nitrobenzylidenephosphorane and a series of substituted benzaldehydes.Values of ΔVexcit. lie in the range -20 to -30 cm3mol-1 and are somewhat solvent-dependent.These measurements are in agreement with the accepted reaction mechanism and suggest that the scope of the reaction may be extended by the use of high pressures.
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