Chemistry Letters p. 331 - 334 (1992)
Update date:2022-08-16
Topics:
Takahashi, Tamotsu
Suzuki, Noriyuki
Hasegawa, Maki
Nitto, Yu
Aoyagi, Ko-ichiro
Saburi, Masahiko
Reactions of zirconocene-alkene complexes with aldehydes gave alcohols as coupling products after hydrolysis.The carbon-carbon bond formation proceeded at C1 carbon of alkenes, in sharp contrast to the reactions of alkene-alkene coupling on zirconium.A similar alcohol was also obtained by the reaction of zirconacyclopentane with aldehyde after hydrolysis.Treatment of (C5Me5)2ZrEt2 with styrene gave 2-phenylbutane after hydrolysis contrary to the case of Cp2ZrEt2 which afforded 1-phenylbutane.
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