Birch reductions at room temperature with alkali metals in silica gel (Na2K-SG(I))

DOI: 10.1021/jo900904f

Source and publish data:

Journal of Organic Chemistry p. 5790 - 5792 (2009)

Update date:2022-08-11

Topics:

Authors:

Nandi, Partha

Dye, James L.

Jackson, James E.

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Article abstract of DOI:10.1021/jo900904f

(Chemical Equation Presented) Alkali metals in silica gel (the Na ₂K-SG(I) reagent) cleanly effect Birch reductions of substrates with at least two or more aromatic rings. The reaction conditions are alcohol-free, ammonia-free, and achieve excellent yields and high selectivities at room temperature.

Full text of DOI:10.1021/jo900904f

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