Bulletin of the Chemical Society of Japan p. 1779 - 1783 (1992)
Update date:2022-08-30
Topics:
Futamura, Shigeru
The electron transfer photooxygenations of aromatic compounds were carried out with trityl salts.Under these superoxide-free reactions conditions, only anthracene and 1,1-diarylethylenes were photooxygenated, stilbenes isomerized, and quantitatively recovered were naphthalene, phenanthrene, alkylnaphthalenes, tetraphenylethylen and 1,1,4,4-tetraaryl-1,3-butadienes.The reactivities of their radical cations toward triplet oxygenation were discussed on the basis of the quantum yield measurements and product analyses.
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